全文获取类型
收费全文 | 3194篇 |
免费 | 809篇 |
国内免费 | 341篇 |
专业分类
化学 | 1367篇 |
晶体学 | 22篇 |
力学 | 355篇 |
综合类 | 21篇 |
数学 | 42篇 |
物理学 | 2537篇 |
出版年
2024年 | 6篇 |
2023年 | 27篇 |
2022年 | 85篇 |
2021年 | 96篇 |
2020年 | 110篇 |
2019年 | 100篇 |
2018年 | 91篇 |
2017年 | 137篇 |
2016年 | 158篇 |
2015年 | 166篇 |
2014年 | 218篇 |
2013年 | 312篇 |
2012年 | 222篇 |
2011年 | 279篇 |
2010年 | 190篇 |
2009年 | 226篇 |
2008年 | 225篇 |
2007年 | 229篇 |
2006年 | 205篇 |
2005年 | 179篇 |
2004年 | 135篇 |
2003年 | 121篇 |
2002年 | 134篇 |
2001年 | 101篇 |
2000年 | 104篇 |
1999年 | 77篇 |
1998年 | 76篇 |
1997年 | 47篇 |
1996年 | 41篇 |
1995年 | 50篇 |
1994年 | 36篇 |
1993年 | 34篇 |
1992年 | 24篇 |
1991年 | 18篇 |
1990年 | 19篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 12篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有4344条查询结果,搜索用时 296 毫秒
101.
《Journal of separation science》2018,41(5):1156-1163
We have developed a reliable, fast, and highly sensitive analytical method utilizing dispersive liquid–liquid microextraction and gold nanoparticles probes for ziram (zinc bis(dimethyldithiocarbamate)) determination. The method is based on the in situ formation of gold nanoparticles in carbon tetrachloride as an organic phase. It was found that the trace levels of ziram influenced the formation of gold nanoparticles, leading to absorbance change of a sedimented phase. The results of the colorimetric ziram determination were in the concentration range of 0.12–2.52 ng/mL with a limit of detection of 0.06 ng/mL. The formation of the stable and dispersed gold nanoparticles in the organic phase provides a good precision for dispersive liquid–liquid microextraction method, resulting in the relative standard deviation of 3.8 and 1.2% for 0.56 and 1.58 ng/mL of ziram, respectively. This method has been successfully used for the ziram determination in samples of well and river water, soil, potato, carrot, wheat, and paddy soil. 相似文献
102.
103.
Tomohiro Takano Chutiparn Lertvachirapaiboon Yasuo Ohdaira Akira Baba Keizo Kato 《Molecular Crystals and Liquid Crystals》2019,685(1):93-99
AbstractGas sensing by using the transmission surface plasmon resonance (T-SPR) technique was demonstrated. Polyacrylic acid (PAA)/5-nm-thick gold/40-nm-thick silver/polycarbonate grating substrate structure (Sensor A) responded to ammonia; however, it exhibited a strong humidity dependence. Polyvinyl alcohol (PVA)/5-nm-thick gold/40-nm-thick silver/polycarbonate grating substrate structure (Sensor B) as the sensing material was also prepared and it mainly responded to humidity. The T-SPR properties of Sensors A and B were observed simultaneously by a stacking arrangement that enabled us to obtain the responses by using a single spectrophotometer. The ammonia concentration under various humidity conditions could be accurately obtained by simultaneous measurement of Sensors A and B. 相似文献
104.
《Physics letters. A》2020,384(23):126564
In terahertz frequency region, we have investigated theoretically the correlation between spectra of a free photonic structure and that deposited on a metal for several models of metal. It was found that for quasi-normal incidence of p-polarized electromagnetic field the presence of metal generates narrow spectral wells in the middle of reflection windows existing in a free photonic crystal. Quite another manifestation of metal-resonator inter-influence takes place at incident angles exceeding the Brewster angle when reflection spikes coincide with modes of photonic crystal resonator and they are absent throughout the stopband areas. The effects are strongly depended on polarization, number of periods and angle of incidence. 相似文献
105.
采用电磁场有限元方法,数值模拟了孔径型扫描近场光学显微镜(aperture Scanning Near-field Optical Microscopy,a-SNOM)在照明模式下的工作过程.针对金偶极天线结构,改变天线长度和纳米间隙尺寸,计算了a-SNOM探针孔径的远场辐射速率随探针端面中心坐标变化的扫描曲线,实现了超越a-SNOM探针通光孔径尺寸的天线金属纳米间隙的超分辨测量,对于100nm通光孔径的探针,可分辨最小尺寸为10nm(0.016倍波长)的金属间隙.通过对比金属和介质偶极天线的a-SNOM探针远场辐射速率测量的计算结果,表明天线金属纳米间隙的超分辨测量的实现是由于金属间隙表面等离激元的激发. 相似文献
106.
Photoluminescence of green nanophosphors Sr2MgSi2O7 doped with Tb3+ under 374-nm excitation 下载免费PDF全文
A series of Sr2MgSi2O7:Tb3+ nanophosphors is prepared using a high-temperature solid-state reaction. The x-ray diffraction patterns show that the crystal structure of the sample is not significantly affected by Tb3+ ions. However, the images of the scanning electron microscope illustrate that the average size of nanoparticles becomes larger with the increase of Tb3+ concentration. Unlike earlier investigations on down-conversion emission of Tb3+ ion excited by deep ultraviolet light, in this work, the photoluminescence characteristics of Sr2MgSi2O7 nanophosphors doped with different Tb3+ concentrations are analyzed under 374-nm excitations. The intense green emission at 545 nm is observed at an optimal doping concentration of 1.6 mol%. The main reason for the concentration quenching is due to the electric dipole-electric dipole interaction among Tb3+ ions. 相似文献
107.
The stabilization of partially-premixed jet flames in the presence of high potential electric fields
Numerous research efforts have focused on flame stabilization and emissions. Based on initial experiments, specific mechanisms resulting from DC electric fields were chosen to be investigated, namely the chemical, thermal, and ionization mechanisms. Numerical simulations were performed on premixed propane-ozone-air flames to characterize ozone effects on flame speed resulting from the formation of ozone in high potential electric fields. These results were compared against partially premixed flame experiments to observe the dominant influences within leading edge stabilization within high potential electric fields. It was found that the electromagnetic or ionization influences, serve as the dominant effect on the combustion zone. 相似文献
108.
We study the linear and nonlinear properties of two-dimensional matter-wave pulses in disk-shaped superfluid Fermi gases.A Kadomtsev-Petviashvili I(KPI) solitary wave has been realized for superfluid Fermi gases in the limited cases of Bardeen-Cooper-Schrieffer(BCS) regime,Bose-Einstein condensate(BEC) regime,and unitarity regime.Onelump solution as well as one-line soliton solutions for the KPI equation are obtained,and two-line soliton solutions with the same amplitude are also studied in the limited cases.The dependence of the lump propagating velocity and the sound speed of two-dimensional superfluid Fermi gases on the interaction parameter are investigated for the limited cases of BEC and unitarity. 相似文献
109.
《Physics letters. A》2014,378(26-27):1871-1875
Optical toroidal resonance in structural variations of the double-disk metamaterial, in viewpoint of an equivalent LC-circuit model, is numerically studied to optimize its geometrically-dependent optical characteristics, such as the enhancement capability of local-field confinement and the extinction coefficient. Responses of high-order magnetic vortex resonances (i.e., the double- and triple-fold vortex modes), in addition to the fundamental toroidal dipole, are excited in accordance with a standing-wave model of oscillating current. The induced strengths for these vortex responses are sensitive, in different manners, to the incident angle of the light, though their frequencies are angularly independent. 相似文献
110.
G. Brunner 《Isotopes in environmental and health studies》2013,49(9-10):328-333
Mit Berücksichtigung eines die horizontale Probeausdehnung umfassenden Geometriefaktors werden unter praktisch brauchbaren Bedingungen absolute Fluoreszens- und Streustrahlungsausbeuten für sättigungsdicke und für dünne Proben berechnet. Die aus ihnen herleitbaren Meβempfindlichkeiten zeigen, daβ sich geringe Konzentrationen von relativ leichten bis mittelschweren Elementen besonders gut messen lassen, wenn man entweder dicht oberhalb der Absorptionskanten liegenda Energien anwendel oder bei relativ hoher Anregungsenergie die Streustahlung abtrennt. Bei groβen Konzentrationen solcher Elemente kann auch ohne Streustrahlungsabtrennung mit relativ hohen Anregungsenergien gemessen werden, wobei sogar unter gewissen Bedingungen mit Zunahme der Anregungsenergie eine leichte Empfindlichkeitsverbesserung eintritt. Bei schweren Elementen ist der Gesichtspunkt der Probendicke vielfach wichtiger als die Wahl der Anregungsenergie. Für dūnne Proben lassen sich relativ recht hohe Empfindlichkeiten erzielen, was jedoch zu einem Problem der absoluten Intensitāten angesichts des Detektor-Strahlungsuntergrundes fūhren kann. 相似文献